Smart, self-healing hydrogels open far-reaching possibilities in medicine, engineering

ScienceDaily (Mar. 5, 2012) ? University of California, San Diego bioengineers have developed a self-healing hydrogel that binds in seconds, as easily as Velcro, and forms a bond strong enough to withstand repeated stretching. The material has numerous potential applications, including medical sutures, targeted drug delivery, industrial sealants and self-healing plastics, a team of UC San Diego Jacobs School of Engineering researchers reported March 5 in the online Early Edition of the Proceedings of the National Academy of Sciences.

Hydrogels are made of linked chains of polymer molecules that form a flexible, jello-like material similar to soft-tissues. Until now, researchers have been unable to develop hydrogels that can rapidly repair themselves when a cut was introduced, limiting their potential applications. The team, led by Shyni Varghese, overcame this challenge with the use of "dangling side chain" molecules that extend like fingers on a hand from the primary structure of the hydrogel network and enable them to grasp one another.

"Self-healing is one of the most fundamental properties of living tissues that allows them to sustain repeated damage," says Varghese. "Being bioengineers, one question that repeatedly appeared before us was if one could mimic self-healing in synthetic, tissue-like materials such as hydrogels. The benefits of creating such an aqueous self-healing material would be far-reaching in medicine and engineering."

To design the side chain molecules of the hydrogel that would enable rapid self-healing, Varghese and her collaborators performed computer simulations of the hydrogel network. The simulations revealed that the ability of the hydrogel to self-heal depended critically on the length of the side chain molecules, or fingers, and that hydrogels having an optimal length of side chain molecules exhibited the strongest self-healing. When two cylindrical pieces of gels featuring these optimized fingers were placed together in an acidic solution, they stuck together instantly. Varghese's lab further found that by simply adjusting the solution's pH levels up or down, the pieces weld (low pH) and separate (high pH) very easily. The process was successfully repeated numerous times without any reduction in the weld strength.

Ameya Phadke, a fourth year PhD student in Varghese's lab said the hydrogel's strength and flexibility in an acidic environment -- similar to that of the stomach -- makes it ideal as an adhesive to heal stomach perforations or for controlled drug delivery to ulcers.

Such healing material could also be useful in the field of energy conservation and recycling where self-healing materials could help reduce industrial and consumer waste, according to Varghese. Additionally, the rapidity of self-healing in response to acids makes the material a promising candidate to seal leakages from containers containing corrosive acids. To test this theory, her lab cut a hole in the bottom of a plastic container, "healed" it by sealing the hole with the hydrogel and demonstrated that it prevented any leakage of acid through the hole.

Moving forward, Varghese and her lab hope to test the material in its envisioned applications on a larger scale. The team also hopes to engineer other varieties of hydrogels that self-heal at different pH values, thereby extending the applications of such hydrogels beyond acidic conditions.

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The above story is reprinted from materials provided by University of California - San Diego.

Note: Materials may be edited for content and length. For further information, please contact the source cited above.

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Journal Reference:

1. Ameya Phadke, Chao Zhang, Bedri Arman, Cheng-Chih Hsu, Raghunath A. Mashelkar, Ashish K. Lele, Michael J. Tauber, Gaurav Arya, and Shyni Varghese. Rapid self-healing hydrogels. Proceedings of the National Academy of Sciences, March 5, 2012 DOI: 10.1073/pnas.1201122109

Note: If no author is given, the source is cited instead.

Disclaimer: This article is not intended to provide medical advice, diagnosis or treatment. Views expressed here do not necessarily reflect those of ScienceDaily or its staff.

Source: http://www.sciencedaily.com/releases/2012/03/120305160650.htm

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Self Growth Techniques for Personal Success

What is self growth? It is about shaping yourself to become a better person with solid values, ethics and a well balanced approach to life.? It is the process of working on your areas of improvement and turning them into areas of strength and opportunities. Just how can you do that? Here are five simple techniques for starters:

?

1. Learn from others. Start with your immediate family and closest friends. What are some of their traits that you admire? What have they accomplished that makes you want to be like them? Talk to them and ask them what they did to achieve self growth that led to their professional and personal success. Then check out famous people whose work you admire and read articles on how they got to the top of their profession. Learn as much as you can about their individual techniques and see which ones you can adopt for yourself.

?

2. Observe admirable people. Look at how they conduct themselves, from the way they walk, talk, sit and generally behave in public. Such refinement can only be a product of effective self growth techniques, which include polishing one?s looks, movements and skill sets to complete the overall package of the person. Look at how they treat others and are treated in turn. You can take a page out of their demeanor to propel yourself towards personal success and professional recognition. This isn?t to say you should mimic their every move; just derive the best practices possible from them that you can employ for your own good.

?

3. Assess your own attitude. How have you been behaving by your lonesome? Are you a person of integrity ? always doing the right thing even when no one is looking? How are you with other people around? Do you exercise kindness and consideration for others, or are you being fueled by your own selfish needs for personal success? Bear in mind that in order to succeed at self growth, you must possess a mature disposition and a kind heart. Aim to be a caring and morally upright person no matter where you go. The universe has a way of rewarding people who treat others well and punishing those who won?t hesitate to trample on the feelings and rights of others.

?

4. Envision the kind of person you would like to be one day. This is a great self growth exercise that can provide you inspiration on your journey to professional and personal success. Paint a picture of the Ideal You ? the kind of individual you wish to become in the future. How do you see yourself in that image? Do you see a nation-building politician, the next Mother Teresa, or the next Steve Jobs? Use your imagination as your mood board to guide you as you work on your greatest ambition.

?

5. Get rid of vices that may be harmful to your self growth. Are you quick to turn to painkillers when you feel the slightest muscle twitch? Do you tend to gorge on sugary snacks and drinks to keep your energy levels up as you slave over a very important project? Remove all self destructive habits from your system and start living clean! You won?t be able to enjoy personal success if your health takes a nosedive and renders you bedridden most of the time. So go have that physical check up and get tips from your physician and nutritionist on how to live a healthier and more wholesome lifestyle.

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The change starts within you. Find your purpose, work on it and remember to enjoy the journey as well. Good luck and may you serve as an inspiring role model to others.

Source: http://lifestyle.ezinemark.com/self-growth-techniques-for-personal-success-7d33f517e174.html

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